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Diesel Deep Hydrotreating Catalyst

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Product Name: Diesel Deep Hydrotreating Catalyst
Model: HHMDS系列
Exhibitors: Lihua
Product Documentation: No Related Documents

Brief

Diesel Deep Hydrotreating Catalyst is suitable to deep hydrotreating process for straight-run diesel, coking diesel, catalytic diesel and coking mixture of gasoline & diesel.


Detail Description

1.  Application

Diesel Deep Hydrotreating Catalyst is suitable to deep hydrotreating process for straight-run diesel, coking diesel, catalytic diesel and coking mixture of gasoline & diesel.

2. Product Features

This series of catalyst has even & effective active component, high dispersion degree, high activity and low loading density, which is specially used to strengthen hydrotreating of Dimethyl DBT sulfide, and helpful for next process of direct hydrodesulfurization which could improve activity of catalyst.

HHMDS-1 catalyst is suitable to high sulfur secondary process diesel on deep desulfurization, removal of olefin basis on high space velocity and low hydrogen/oil ratio. Sulfur in product meets demand of standard Europe III, Europe IV and Europe V basis on existing hydrotreating unit of 6.0~8.0 MPa pressure and 1.0~2.5 h-1 space velocity. Specially suitable to deep hydrotreating of straight-run diesel, coking gasoline & diesel, coking diesel.

HHMDS-2 is specially for high sulfur high nitrogen diesel. We developed unique carrier for this catalyst, one-time impregnated, active optimized auxiliaries which are making catalyst works excellent on deep desulfurization, denitrification and de-aromatic hydrocarbon.

Comparing to other similar catalysts, HHMDS-2 reacts at 5℃ lower and 20% more activity.

Specially suitable to deep hydotreating process of straight-run diesel&gasoline, coking diesel&gasoline, coking diesel and distillate pre-hydrogenation such as FCC material and hydrocracking material.

 
3.  Chemical Composition and Physical Properties
Catalyst type
HHMDS-1
HHMDS-2
Active component
W-Mo-Ni
Mo-Ni
Active composition, wt%
≦30
~28
Shape
clover
trefoil
Diameter, mm
Ф1.5~2.0
Ф1.3~ 1.6
Pore volume cm/g
≧0.30
≧0.30
Surface area, m2/g
≧200
≧180
Bulk density, g/mL
≦0.75
0.75~0.83
Crush strength, N/cm
≧150
≧150
4. Operation Condition
     Pressure: 6~12MPa
    Temperature: 340~380℃
    Space velocity: 0.5~2.5 h-1
   Hydrogen/oil ratio: 300~800
 
5.  Operation Example

 Example 1

Raw oil

Mixture of straight-run diesel, catalytic diesel and coking diesel

Operation condition

Hydrogen partial pressure, MPa

6.18

Inlet temperature,

308

Space velocity, h-1

1.8

Oil properties

raw oil

hydrotreated diesel oil

Density (20), g/m3

861.6

840.4

95% point,

363

355

Sulfur, mg/g

11200

290

Nitrogen, mg/g

353

44.1


Example 2

Catalyst

Value

Primary operation condition

Pressure, MPa

4~6

Space velocity, h-1

1.0~2.5

Temperature,

250~300

Hydrogen/oil ratio

300~500

(20)Density, g/cm3

0.8087

Distillation,

IBP

186

10%

192

50%

204

90%

224

EBP

230

Sulfur, μg/g

520

<5

Nitrogen, μg/g

9.8

<1

Bromine index, mgBr/100g

1160

168

Basic nitrogen, μg/g

4.2

0.22

 

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