Metallurgy catalyst
AD-946 Ammonia Decomposition Catalyst
AD-946 Ammonia Decomposition Catalyst is cooperatively developed by our company and chemical physics research institute in Dalian of Chinese Academy of Sciences, for insteading of Germany G-117. It is provided with the properties of great catalytic activity, high mechanical strength, and excellent thermal and coking resistance. It is used in the ammonia decomposing furnace to decompose the NH3 and HCN etc. into N2, H2 and CO2, and so as to effectively purify the coke-oven gas for the sake of environmental protection and prevent the equipment from corrosion.
Technical Feature
a. Chemical reaction
NH3 → 0.5 N2 + 1.5H2
2HCN + 2H2O + O2→ N2 + 5H2 + 2CO2
b.Technical Indexes
Type
Item
|
AD-946
|
AD-946 A
|
AD-946 B
|
Color
|
Grey and Black
|
Shape
|
Cylinder
|
Rasching Ring
|
Honeycomb
|
Size, mm
|
Φ18×20
|
Φ18×20×5
|
Φ18×20
|
Ni Content, %
|
≥6
|
≥6
|
≥6
|
Bulk density, g/ml
|
1.4 ~ 1.6
|
1.3 ~ 1.5
|
1.2 ~1.5
|
Surface area, m2/g
|
1 ~ 3
|
2 ~ 4
|
2 ~ 5
|
Crushing strength, N
|
≥1000
|
≥1000
|
≥1100
|
Thermal resistance, ℃
|
≥1350
|
≥1350
|
≥1350
|
Normal Operating Conditions
Operating Temperature
|
1000~1200℃
|
Maximum Teperature
|
1350℃
|
Pressure
|
0.1~1MPa
|
Space Velocity
|
1000~3000 h-1
|
NH3 Decomposing Rate
|
≧94%
|
Petrochemical Catalysts
Light Distillate Hydrotreating Catalyst HHLDS Series
Application
According to that light distillate has different features from different refinery depends on raw material and operation condition, HHLDS series catalyst is specially developed for reforming pre-hydrogenation, solvent oil hydrotreating and Kerosene hydrotreating.
Chemical Composition and Physical Properties
Catalyst type
|
HHLDS-1
|
HHLDS-2
|
HHLDS-3
|
Active metal
|
Mo-Co
|
Mo-Ni
|
Mo-Ni-Co
|
Shape
|
sphere
|
trefoil
|
trefoil
|
Diameter, mm
|
f1.5~2.5
|
f1.5~2.5
|
f1.5~2.5
|
Pore volume,mL.g-1
|
≧0.40
|
≧0.40
|
≧0.42
|
Surface area, m2.g-1
|
≧200
|
≧200
|
≧220
|
Crush strength, N/pcs
|
≧40
|
≧140
|
≧140
|
Bulk density, g/cm
|
0.68~0.78
|
0.68~0.78
|
0.65~0.75
|
Operation Condition
Reforming Prehydrogenation
|
Reaction pressure
|
1.6~2.4 MPa
|
Temperature
|
270~320 ℃
|
volume space velocity
|
6.0~8.0 h-1
|
hydrogen/oil volume ratio
|
80~150
|
Coking naphtha and pyrolysis gasoline Hydrotreating
|
Reaction pressure
|
3.0~4.0 MPa
|
Temperature
|
180~280 ℃
|
volume space velocity
|
1.6~4.0 h-1
|
hydrogen/oil volume ratio
|
300~600
|
Diesel Deep Hydrotreating Catalyst
hydrotreating catalyst is suitable to deep hydrotreating process for straight-run diesel, coking diesel, catalytic diesel and coking mixture of gasoline & diesel.
Chemical Composition and Physical Properties
Catalyst type
|
HHMDS-1
|
THDS-II
|
Active component
|
W-Mo-Ni
|
Mo-Ni
|
Active composition, wt%
|
≦30
|
~28
|
Shape
|
clover
|
trefoil
|
Diameter, mm
|
Ф1.5~2.0
|
Ф1.3~ 1.6
|
Pore volume cm/g
|
≧0.30
|
≧0.30
|
Surface area, m2/g
|
≧200
|
≧180
|
Bulk density, g/mL
|
≦0.75
|
0.75~0.83
|
Crush strength, N/cm
|
≧150
|
≧150
|
Chemical Fertilizer Catalyst
Primary Reforming Catalys
Product Description
Primary Reforming Catalyst HHZ01 is mainly used in primary reformer to produce synthesis ammonia or hydrogen, which is mainly for steam and methane gas such as natural gas, oil field gas, coke-oven gas, refinery gas and so on. This item has been proved has excellent activity at low temperature, good resistance of carbon reforming, high crush strength, small resistance, easy to reduce & loading etc.
Chemical Composition and Physical Properties
NiO
|
≥14.5wt%
|
SiO2
|
≤0.2 wt%
|
Fe2O3
|
≤0.35 wt%
|
Physical
|
Typical properties
|
Item
|
Value
|
Appearance
|
Grey 3-hole3 flute cylinder (domed)
|
Grey 4-hole 4 flute cylinder (domed)
|
Diameter
|
14mm
|
17mm
|
Length
|
11mm
|
17mm
|
Internal hole diameter
|
4.5mm
|
4.5mm
|
Loaded density
|
1000-1100 Kg/m3
|
1000-1100 Kg/m3
|
Average crush strength (radial)
|
≥250 N
|
≥250 N
|
Specific surface area
|
3.0-5.0 m2/g
|
3.0-5.0 m2/g
|
Operating condition
Normal condition, HHH01 could have good activity at 600℃.
Inlet temperature: 400—650℃
Outlet temperature: 650-950℃
Operation condition: 0.7~5.0MPa
Carbon space velocity ≤2500h-1
water/carbon ratio≥2.5
Gas feed up require H2S≤0.5×10-6 (0.5PPm)
Secondary Reforming Catalyst
Secondary reforming catalyst is kind of Precipitation type reforming catalyst taking nickel as active component and alumina as carrier, which is mainly used for secondary steam reforming process using methane gas as raw material such as natural gas, oil field gas, coke-oven gas, refinery gas.
Secondary reformer works with high temperature, LHZ02Y catalyst need to resistant to higher temperature than primary reforming catalyst. Use along with LHZ03Y guard catalyst would make them work well with excellent crush strength and resistance to 1300℃.
Typical Chemical Composition and Physical Properties
Item
|
LHZ03Y
|
LHZ02Y
|
Appearance
|
Grey rasching ring
|
5 holes 4flute (Domed)
|
Spec
s (OD*ID*H)
|
Φ25×(10~15) mm
|
Φ19×4.5×(18~20)mm
|
Bulk density, Kg/L
|
1.0±0.05
|
1.0±0.05
|
Crush strength, N/pcs
|
≥400
|
≥400
|
NiO, %
|
≥6.0
|
≥14.0
|
SiO2, %
|
≤0.2
|
≤0.2
|
K2O+Na2O, %
|
≤0.2
|
≤0.2
|
CaO, %
|
0
|
≤10
|
Loss on ignition, %
|
≤7
|
≤7
|
Methanation Catalyst
LHMC01 methanation catalyst is of Titanium rare earth nickel catalyst which is suitable for synthesis ammonia unit or hydrogen plant, to remove CO and CO2 at low concentration and make them to be inert gas, methane and water.
This catalyst has high crush strength, large pore volume, high activity and easily to be unloading. It has been obviously performing much better than other similar catalyst under high pressure and high space velocity.
Technology Parameter
Chemical composition
Item
|
Parameter
|
NiO
|
18±1.0%
|
TiO2
|
6-8%
|
Auxiliaries
|
4±0.5%
|
Auxiliaries
|
2%
|
Al2O3%
|
balance
|
Physical water
|
Almost 0
|
volume shrinkage
|
Almost 0
|
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